Reprint of “Seasonal and daily variation of mercury evasion at coastal and off shore sites from the Mediterranean Sea”     

Maria E. Andersson  Katarina Gårdfeldt  Ingvar Wängberg  Francesca Sprovieri  Nicola Pirrone  Oliver Lindqvist 《Marine Chemistry》2007

Dissolved gaseous mercury (DGM) was measured continuously using two newly developed techniques and a manual technique. The continuous techniques were based on the equilibrium between the aqueous and gaseous phase (DGM = Hg_extr / H', Hg_extr is the measured mercury concentration in the gas phase, H' is the Henry's Law coefficient at the desired temperature). In order to calculate the annual mercury evasion from the Mediterranean Sea, diurnal and seasonal measurements of DGM, total gaseous mercury in air (TGM), water temperature and wind speed were performed. During August 2003, March–April 2004 and October–November 2004 measurements of these parameters were conducted on board the RV Urania. The continuous measurements of DGM showed a diurnal variation in concentration, at both coastal and off shore sites, with higher concentrations during daytime than nighttime. The concentration difference could be as large as 130 fM between day and night. The degree of saturation was calculated directly from the measurements, S = Hg_extr / TGM and was found to vary between the different seasons. The highest average degree of saturation (850%) and the largest variation in saturation (600–1150%) was observed during the summer. The spring showed the lowest variation (260–360%) and the lowest average degree of saturation (320%). The autumn also showed a large variation in saturation (500–1070%) but a lower average (740%) compared to the summer cruise. This might be explained by the temperature difference between the different seasons, since that parameter varied the most. The flux from the sea surface was calculated using the gas exchange model developed by Nightingale et al. [Nightingale, P.D., Malin, G., Law, C.S., Watson, A.J., Liss, P.S., Liddicoat, M.I., Boutin, J., Upstill-Goddard, R. C., 2000. In situ evaluation of air–sea gas exchange parameterization using novel conservative and volatile tracers. Global Biogeochemical Cycles, 14(1):373–387]. The evasion varied between the different seasons with the highest evasion during the autumn, 24.6 pmol m^− 2 h^− 1. The summer value was estimated to 22.3 pmol m^− 2 h^− 1 and the spring to 7.6 pmol m^− 2 h^− 1. Using this data the yearly evasion from the Mediterranean Sea surface was estimated to 77 tons.  相似文献   

Exchange flux of total gaseous mercury between air and natural water surfaces in summer season   总被引：5，自引：0，他引：5  

冯新斌  Jonas Sommar 《中国科学D辑(英文版)》2002,45(3):211-220

The exchanges of mercury between surface and air are of significance in the biogeochemical cycling of Hg in the environment, but there are still few reliable data on air/surface exchange in aquatic systems. Field measurement campaigns over seawater surface at Kristineberg Marine Research Station (KMRS) and over Hovg?rds?n River surface at Knobesholm in southwestern Sweden were conducted to measure mercury flux using a dynamic flux chamber technique coupled with automatic mercury vapor-phase analyzers. Both sites show net emissions during summer time. Mercury fluxes measured over both river and seawater surfaces exhibit a consistently diurnal pattern with maximum fluxes during the daytime period and minimum fluxes during the nighttime period. At freshwater site, mercury flux is strongly correlated with the intensity of net solar radiation, and negatively correlated with relative humidity. A typical exponential relationship between mercury flux and water temperature was observed at freshwater measurement site. At seawater site, a strong correlation between mercury flux and intensity of solar radiation was obtained. The driving force of mercury emission from water surface to air is the super-saturation of dissolved gaseous mercury in aqueous phase.  相似文献   

Capturing the stories of corporations: A comparison of media debates on carbon capture and storage in Norway and Sweden     

Katarina Buhr  Anders Hansson 《Global Environmental Change》2011,21(2):336-345

The development and deployment of carbon capture and storage (CCS) are sensitive to public debates that socially frame the technology. This study examines the evolving CCS debates, focusing on the media's framing of firms. Corporations are central CCS actors, and we analyze them in light of the nation-state, which has been emphasized in previous research as the primary context of CCS politics. Empirically, we compare framings of Statoil and Vattenfall in the Norwegian and Swedish media, drawing on a qualitative dataset of news media articles published between 2005 and 2009. We conclude that firms make regular media statements either to foster legitimacy or to respond to criticism of CCS. We also conclude that framing is not necessarily linked to technological success or failure and that interpretations of the technology have different forms depending on whether the related activity occurs in domestic or foreign markets. Finally, we explain the media framings based on the domestic energy situation and politics.  相似文献   

Increased hydrocarbon recovery and CO2 storage in Neogene sandstones,a Croatian example: part II     

Karolina Novak  Tomislav Malvić  Josipa Velić  Katarina Simon 《Environmental Earth Sciences》2014,71(8):3641-3653

During 2003–2006, a pilot project of alternating water and CO₂ injection was performed on a limited part of the Upper Miocene sandstone oil reservoir of the Ivani? Field. During the test period oil and gas recovery was significantly increased. Additionally 4,440 m³ of oil and 2.26 × 10⁶ m³ of gas were produced. It has initiated further modelling of sandstone reservoirs in the Ivani? Field in order to calculate volumes available for CO₂ injection for the purpose of increasing hydrocarbon production from depleted sandstone reservoirs in the entire Croatian part of the Pannonian Basin System. In the first phase, modelling was based on results of laboratory testing on the core samples. It considered applying analogies with world-known projects of CO₂ subsurface storage and its usage to enhance hydrocarbon production. In the second phase, reservoir variables were analysed by variograms and subsequently mapped in order to reach lithological heterogeneities and to determine reliable average values of reservoir volumes. Data on porosity, depth and reservoir thickness for the “Gamma 3” and the “Gamma 4” reservoirs, are mapped by the ordinary kriging technique. Calculated volume of CO₂ expressed at standard condition which can be injected in the main reservoirs of the Ivani? Field at near miscible conditions is above 15.5 billion m³.  相似文献   

Hafnium Isotope Characteristics of Palaeoarchaean Zircon OG1/OGC from the Owens Gully Diorite,Pilbara Craton,Western Australia          下载免费PDF全文

Anthony I. S. Kemp  Jeffrey D. Vervoort  Katarina E. Bjorkman  Linda M. Iaccheri 《Geostandards and Geoanalytical Research》2017,41(4):659-673

We report Hf isotope data for 3467 Ma igneous zircons from the Owens Gully Diorite of the Pilbara Craton. These zircons, designated OG1 or OGC, have simple, well‐defined U‐Pb age systematics. Measurements obtained by single crystal dissolution yield a moderate range in ¹⁷⁶Hf/¹⁷⁷Hf (mean 0.280633 ± 34) and ¹⁷⁶Lu/¹⁷⁷Hf (mean 0.00119) that translate into initial (3467 Ma) ¹⁷⁶Hf/¹⁷⁷Hf values that are equivalent within measurement uncertainty (mean 0.280554 ± 7, ε_Hf = +0.6 ± 0.2, 2s). Laser ablation analysis yielded clustered initial ¹⁷⁶Hf/¹⁷⁷Hf ratios (mean 0.280560 ± 20, 2s) indistinguishable from those obtained by solution analysis. The antiquity and moderately high ¹⁷⁶Lu/¹⁷⁷Hf of these zircons result in significant corrections for radiogenic ingrowth of ¹⁷⁶Hf (to 6 ε_Hf units). Depth profiling by concurrent Pb‐Hf isotope determination reveals trends to lower ²⁰⁷Pb/²⁰⁶Pb in several crystals, although these are not accompanied by shifts in ¹⁷⁶Hf/¹⁷⁷Hf. We conclude that zircons from the Owens Gully Diorite are homogeneous for Hf isotopes at the scale of sampling and within the uncertainty limits of the measurement techniques employed. Zircon OG1/OGC would appear to be an ideal quality monitor for laser ablation Hf isotope determination in ancient zircons, and for laser ablation techniques where Hf isotope and age information are determined concurrently or simultaneously.  相似文献   

Multi‐scale assessment of overflow‐driven lateral connectivity in floodplain and backwater channels using LiDAR imagery          下载免费PDF全文

Katarina Džubáková  Hervé Piégay  Jérémie Riquier  Milan Trizna 《水文研究》2015,29(10):2315-2330

Overflow‐driven lateral connectivity significantly influences the spatial distribution and diversity of floodplain habitats and biota. Proper understanding of lateral connectivity in floodplain and backwater channels is therefore critical for assessment of river quality and for targeting management or restoration actions. In this study, we present a methodological framework for spatial and temporal assessments of overflow‐driven lateral connectivity at two spatial scales: bypass reach and backwater channel. Firstly, we compute the relative elevations, as well as overflow discharge, duration, and frequency using a simple, raster‐based method that uses a LiDAR digital elevation model (DEM), rating curves, and streamflow time series. Subsequently, we analyse the accuracy of this approach with respect to the accuracy of a DEM and evaluate its further applications. Altogether, four 10‐km‐long bypass reaches and 11 backwater channels are analysed, located along the Rhône River corridor in France. The results proved the precision of the method to be affected by the LiDAR DEM accuracy, which was on average more precise in a typically homogeneous floodplain setting rather than for backwater channel plugs with pronounced topographic complexity and usually riparian forest canopy. Amongst the four studied reaches, Brégnier Cordon proved to have the greatest flooding dynamics, followed by Belley and Chautagne. The hydrological connectivity pattern of Pierre Bénite differed significantly. Three longitudinal patterns of hydrological connectivity of backwater channels displayed stepwise advancement of the water. The presented results can be used to assess ecological potential of floodplain habitats and their historic and prospective evolution through time. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Development of an incised valley‐fill at an evolving rift margin: Pleistocene eustasy and tectonics on the southern side of the Gulf of Corinth,Greece     

Katarina Gobo  Massimiliano Ghinassi  Wojciech Nemec  Eivind Sjursen 《Sedimentology》2014,61(4):1086-1119

This study from the southern margin of the Gulf of Corinth documents a Late Pleistocene incised valley‐fill succession that differs from the existing facies models, because it comprises gravelly shoal‐water and Gilbert‐type deltaic deposits, shows strong wave influence and lacks evidence of tidal activity. The valley‐fill is at least 140 m thick, formed in 50 to 100 ka between the interglacials Marine Isotope Stage 9a and Marine Isotope Stage 7c. The relative sea‐level rise left its record both inside and outside the incised valley, and the age of the valley‐fill is estimated from a U/Th date of coral‐bearing deposits directly outside the palaeovalley outlet. Tectonic up‐warping due to formation of a valley‐parallel structural relay ramp contributed to the valley segmentation and limited the landward extent of marine invasions. The valley segment upstream of the ramp crest was filled with a gravelly alluvium, whereas the downstream segment accumulated fluvio‐deltaic deposits. The consecutive deltaic systems nucleated in the ramp‐crest zone, forming a bathymetric gradient that promoted the ultimate growth of thick Gilbert‐type delta. The case study contributes to the spectrum of conceptual models for incised valley‐fill architecture. Four key models are discussed with reference to the rates of sediment supply and accommodation development, and it is pointed out that not only similarity, but also all departures of particular field cases from these end‐member models may provide valuable information on the system formative conditions. The Akrata incised valley‐fill represents conditions of high sediment supply and a rapid, but stepwise development of accommodation that resulted from the spatiotemporal evolution of normal faulting at the rift margin and overprinted glacioeustatic signals. This study adds to an understanding of valley‐fill architecture and provides new insights into the Pleistocene tectonics and palaeogeography of the Corinth Rift margin.  相似文献   

Governance,complexity, and resilience   总被引：1，自引：0，他引：1  

Andreas Duit  Victor Galaz  Katarina Eckerberg  Jonas Ebbesson 《Global Environmental Change》2010,20(3):363-368

This special issue brings together prominent scholars to explore novel multilevel governance challenges posed by the behavior of dynamic and complex social-ecological systems. Here we expand and investigate the emerging notion of “resilience” as a perspective for understanding how societies can cope with, and develop from, disturbances and change. As the contributions to the special issue illustrate, resilience thinking in its current form contains substantial normative and conceptual difficulties for the analysis of social systems. However, a resilience approach to governance issues also shows a great deal of promise as it enables a more refined understanding of the dynamics of rapid, interlinked and multiscale change. This potential should not be underestimated as institutions and decision-makers try to deal with converging trends of global interconnectedness and increasing pressure on social-ecological systems.  相似文献   

夏季自然水体与大气界面间气态总汞的交换通量   总被引：10，自引：0，他引：10  

冯新斌  S.Jonas  G.Katarina  L.Oliver 《中国科学D辑》2002,32(7):609-616

利用动力学通量箱法与高时间分辨率大气测汞仪的联用技术, 在瑞典西南的Kristineberg海洋观测站(KMRS)和Knobesholm的Hovgårdsån河分别测定了夏季海水和河水表面与大气间汞的交换通量. 在夏季, 河水和海水都是大气汞的源. 河水和海水表面与大气间汞的交换通量在夏季具有一致的昼夜变化规律, 白天由水体向大气排汞且在正午达到最大值; 夜间排汞量相对较小且有时会出现大气汞向水体沉降. 河水与大气间汞的交换通量与光照强度呈线性正相关关系, 与大气相对湿度呈线性负相关性, 同时还与水体温度存在指数相关性. 海水与大气间汞交换通量只与光照强度存在良好的线性正相关关系. 水体中溶解态气汞的过饱和是水体汞向大气释放的驱动力.  相似文献   

Adsorption of monocarboxylates at the water/goethite interface: The importance of hydrogen bonding     

Katarina Norén 《Geochimica et cosmochimica acta》2007,71(23):5717-5730

The adsorption of monocarboxylates (acetate, benzoate, and cyclohexanecarboxylate) at the water/goethite interface was studied as a function of pH and ionic strength by means of quantitative adsorption measurements and attenuated total reflectance-Fourier transform infrared (ATR-FTIR) spectroscopy. ATR-FTIR spectra were obtained of suspensions prepared in both H₂O and D₂O. In order to identify the number of predominating surface complexes and to improve the resolution of overlapping peaks the ATR-FTIR spectra were subjected to a 2D correlation spectroscopic analysis. The adsorption envelopes of acetate, benzoate, and cyclohexanecarboxylate are similar and depend strongly on pH and ionic strength, but the pH dependence is also correlated to the slightly different pK_a values of the monocarboxylic acids. At the molecular level, the ATR-FTIR spectroscopic results reveal two surface complexes: one solvent-surface hydration-separated ion pair and one surface hydration-shared ion pair. The former predominates at circumneutral pH values while the latter forms mainly in the acidic pH range. We find no evidence for direct inner-sphere coordination between the carboxylic oxygens and the Fe(III) ions present at the surface. The identification of surface hydration-shared ion pairs emphasizes the importance of comparatively strong ionic hydrogen-bonding interactions for adsorption processes at the water/goethite interface.  相似文献